Physical Chemistry 12th edition

Access is contingent on use of this textbook in the instructor's classroom.

• Chapter 1: Focus 1 – The Properties of Gases
  • 1: Integrated Activities
  
  
• Chapter 1A: Topic 1A – The Perfect Gas
  • 1A: Discussion Questions
  • 1A: Exercises
  • 1A: Problems
  • 1A: Extra Problems
  
  
• Chapter 1B: Topic 1B – The Kinetic Model
  • 1B: Discussion Questions
  • 1B: Exercises
  • 1B: Problems
  • 1B: Extra Problems
  
  
• Chapter 1C: Topic 1C – Real Gases
  • 1C: Discussion Questions
  • 1C: Exercises
  • 1C: Problems
  • 1C: Extra Problems
  
  
• Chapter 2: Focus 2 – The First Law
  • 2: Integrated Activities
  
  
• Chapter 2A: Topic 2A – Internal Energy
  • 2A: Discussion Questions
  • 2A: Exercises
  • 2A: Problems
  • 2A: Extra Problems
  
  
• Chapter 2B: Topic 2B – Enthalpy
  • 2B: Discussion Questions
  • 2B: Exercises
  • 2B: Problems
  • 2B: Extra Problems
  
  
• Chapter 2C: Topic 2C – Thermochemistry
  • 2C: Discussion Questions
  • 2C: Exercises
  • 2C: Problems
  • 2C: Extra Problems
  
  
• Chapter 2D: Topic 2D – State Functions and Exact Differentials
  • 2D: Discussion Questions
  • 2D: Exercises
  • 2D: Problems
  • 2D: Extra Problems
  
  
• Chapter 2E: Topic 2E – Adiabatic Changes
  • 2E: Discussion Questions
  • 2E: Exercises
  • 2E: Problems
  • 2E: Extra Problems
  
  
• Chapter 3: Focus 3 – The Second and Third Laws
  • 3: Integrated Activities
  
  
• Chapter 3A: Topic 3A – Entropy
  • 3A: Discussion Questions
  • 3A: Exercises
  • 3A: Problems
  • 3A: Extra Problems
  
  
• Chapter 3B: Topic 3B – Entropy Changes Accompanying Specific Processes
  • 3B: Discussion Questions
  • 3B: Exercises
  • 3B: Problems
  • 3B: Extra Problems
  
  
• Chapter 3C: Topic 3C – The Measurement of Entropy
  • 3C: Discussion Questions
  • 3C: Exercises
  • 3C: Problems
  • 3C: Extra Problems
  
  
• Chapter 3D: Topic 3D – Concentrating on the System
  • 3D: Discussion Questions
  • 3D: Exercises
  • 3D: Problems
  • 3D: Extra Problems
  
  
• Chapter 3E: Topic 3E – Combining the First and Second Laws
  • 3E: Discussion Questions
  • 3E: Exercises
  • 3E: Problems
  • 3E: Extra Problems
  
  
• Chapter 4: Focus 4 – Physical Transformations of Pure Substances
  • 4: Integrated Activities
  
  
• Chapter 4A: Topic 4A – Phase Diagrams of Pure Substances
  • 4A: Discussion Questions
  • 4A: Exercises
  • 4A: Problems
  • 4A: Extra Problems
  
  
• Chapter 4B: Topic 4B – Thermodynamic Aspects of Phase Transitions
  • 4B: Discussion Questions
  • 4B: Exercises
  • 4B: Problems
  • 4B: Extra Problems
  
  
• Chapter 5: Focus 5 – Simple Mixtures
  • 5: Integrated Activities
  
  
• Chapter 5A: Topic 5A – The Thermodynamic Description of Mixtures
  • 5A: Discussion Questions
  • 5A: Exercises
  • 5A: Problems
  • 5A: Extra Problems
  
  
• Chapter 5B: Topic 5B – The Properties of Solutions
  • 5B: Discussion Questions
  • 5B: Exercises
  • 5B: Problems
  • 5B: Extra Problems
  
  
• Chapter 5C: Topic 5C – Phase Diagrams of Binary Systems: Liquids
  • 5C: Discussion Questions
  • 5C: Exercises
  • 5C: Problems
  • 5C: Extra Problems
  
  
• Chapter 5D: Topic 5D – Phase Diagrams of Binary Systems: Solids
  • 5D: Discussion Questions
  • 5D: Exercises
  • 5D: Problems
  • 5D: Extra Problems
  
  
• Chapter 5E: Topic 5E – Phase Diagrams of Ternary Systems
  • 5E: Discussion Questions
  • 5E: Exercises
  • 5E: Problems
  • 5E: Extra Problems
  
  
• Chapter 5F: Topic 5F – Activities
  • 5F: Discussion Questions
  • 5F: Exercises
  • 5F: Problems
  • 5F: Extra Problems
  
  
• Chapter 6: Focus 6 – Chemical Equilibrium
  • 6: Integrated Activities
  
  
• Chapter 6A: Topic 6A – The Equilibrium Constant
  • 6A: Discussion Questions
  • 6A: Exercises
  • 6A: Problems
  • 6A: Extra Problems
  
  
• Chapter 6B: Topic 6B – The Response of Equilibria to the Conditions
  • 6B: Discussion Questions
  • 6B: Exercises
  • 6B: Problems
  • 6B: Extra Problems
  
  
• Chapter 6C: Topic 6C – Electrochemical Cells
  • 6C: Discussion Questions
  • 6C: Exercises
  • 6C: Problems
  • 6C: Extra Problems
  
  
• Chapter 6D: Topic 6D – Electrode Potentials
  • 6D: Discussion Questions
  • 6D: Exercises
  • 6D: Problems
  • 6D: Extra Problems
  
  
• Chapter 7: Focus 7 – Quantum Theory
  • 7: Integrated Activities
  
  
• Chapter 7A: Topic 7A – The Origins of Quantum Mechanics
  • 7A: Discussion Questions
  • 7A: Exercises
  • 7A: Problems
  • 7A: Extra Problems
  
  
• Chapter 7B: Topic 7B – Wavefunctions
  • 7B: Discussion Questions
  • 7B: Exercises
  • 7B: Problems
  • 7B: Extra Problems
  
  
• Chapter 7C: Topic 7C – Operators and Observables
  • 7C: Discussion Questions
  • 7C: Exercises
  • 7C: Problems
  • 7C: Extra Problems
  
  
• Chapter 7D: Topic 7D – Translational Motion
  • 7D: Discussion Questions
  • 7D: Exercises
  • 7D: Problems
  • 7D: Extra Problems
  
  
• Chapter 7E: Topic 7E – Vibrational Motion
  • 7E: Discussion Questions
  • 7E: Exercises
  • 7E: Problems
  • 7E: Extra Problems
  
  
• Chapter 7F: Topic 7F – Rotational Motion
  • 7F: Discussion Questions
  • 7F: Exercises
  • 7F: Problems
  • 7F: Extra Problems
  
  
• Chapter 8: Focus 8 – Atomic Structure and Spectra
  • 8: Integrated Activities
  
  
• Chapter 8A: Topic 8A – Hydrogenic Atoms
  • 8A: Discussion Questions
  • 8A: Exercises
  • 8A: Problems
  • 8A: Extra Problems
  
  
• Chapter 8B: Topic 8B – Many-Electron Atoms
  • 8B: Discussion Questions
  • 8B: Exercises
  • 8B: Problems
  • 8B: Extra Problems
  
  
• Chapter 8C: Topic 8C – Atomic Spectra
  • 8C: Discussion Questions
  • 8C: Exercises
  • 8C: Problems
  • 8C: Extra Problems
  
  
• Chapter 9: Focus 9 – Molecular Structure
  • 9: Integrated Activities
  
  
• Chapter 9A: Topic 9A – Valence-Bond Theory
  • 9A: Discussion Questions
  • 9A: Exercises
  • 9A: Problems
  • 9A: Extra Problems
  
  
• Chapter 9B: Topic 9B – Molecular Orbital Theory: The Hydrogen Molecule-Ion
  • 9B: Discussion Questions
  • 9B: Exercises
  • 9B: Problems
  • 9B: Extra Problems
  
  
• Chapter 9C: Topic 9C – Molecular Orbital Theory: Homonuclear Diatomic Molecules
  • 9C: Discussion Questions
  • 9C: Exercises
  • 9C: Problems
  • 9C: Extra Problems
  
  
• Chapter 9D: Topic 9D – Molecular Orbital Theory: Heteronuclear Diatomic Molecules
  • 9D: Discussion Questions
  • 9D: Exercises
  • 9D: Problems
  • 9D: Extra Problems
  
  
• Chapter 9E: Topic 9E – Molecular Orbital Theory: Polyatomic Molecules
  • 9E: Discussion Questions
  • 9E: Exercises
  • 9E: Problems
  • 9E: Extra Problems
  
  
• Chapter 10: Focus 10 – Molecular Symmetry
  • 10: Integrated Activities
  
  
• Chapter 10A: Topic 10A – Shape and Symmetry
  • 10A: Discussion Questions
  • 10A: Exercises
  • 10A: Problems
  • 10A: Extra Problems
  
  
• Chapter 10B: Topic 10B – Group Theory
  • 10B: Discussion Questions
  • 10B: Exercises
  • 10B: Problems
  • 10B: Extra Problems
  
  
• Chapter 10C: Topic 10C – Applications of Symmetry
  • 10C: Discussion Questions
  • 10C: Exercises
  • 10C: Problems
  • 10C: Extra Problems
  
  
• Chapter 11: Focus 11 – Molecular Spectroscopy
  • 11: Integrated Activities
  
  
• Chapter 11A: Topic 11A – General Features of Molecular Spectroscopy
  • 11A: Discussion Questions
  • 11A: Exercises
  • 11A: Problems
  • 11A: Extra Problems
  
  
• Chapter 11B: Topic 11B – Rotational Spectroscopy
  • 11B: Discussion Questions
  • 11B: Exercises
  • 11B: Problems
  • 11B: Extra Problems
  
  
• Chapter 11C: Topic 11C – Vibrational Spectroscopy of Diatomic Molecules
  • 11C: Discussion Questions
  • 11C: Exercises
  • 11C: Problems
  • 11C: Extra Problems
  
  
• Chapter 11D: Topic 11D – Vibrational Spectroscopy of Polyatomic Molecules
  • 11D: Discussion Questions
  • 11D: Exercises
  • 11D: Problems
  • 11D: Extra Problems
  
  
• Chapter 11E: Topic 11E – Symmetry Analysis of Vibrational Spectra
  • 11E: Discussion Questions
  • 11E: Exercises
  • 11E: Problems
  • 11E: Extra Problems
  
  
• Chapter 11F: Topic 11F – Electronic Spectra
  • 11F: Discussion Questions
  • 11F: Exercises
  • 11F: Problems
  • 11F: Extra Problems
  
  
• Chapter 11G: Topic 11G – Decay of Excited States
  • 11G: Discussion Questions
  • 11G: Exercises
  • 11G: Problems
  • 11G: Extra Problems
  
  
• Chapter 12: Focus 12 – Magnetic Resonance
  • 12: Integrated Activities
  
  
• Chapter 12A: Topic 12A – General Principles
  • 12A: Discussion Questions
  • 12A: Exercises
  • 12A: Problems
  • 12A: Extra Problems
  
  
• Chapter 12B: Topic 12B – Features of NMR Spectra
  • 12B: Discussion Questions
  • 12B: Exercises
  • 12B: Problems
  • 12B: Extra Problems
  
  
• Chapter 12C: Topic 12C – Pulse Techniques in NMR
  • 12C: Discussion Questions
  • 12C: Exercises
  • 12C: Problems
  • 12C: Extra Problems
  
  
• Chapter 12D: Topic 12D – Electron Paramagnetic Resonance
  • 12D: Discussion Questions
  • 12D: Exercises
  • 12D: Problems
  • 12D: Extra Problems
  
  
• Chapter 13: Focus 13 – Statistical Thermodynamics
  • 13: Integrated Activities
  
  
• Chapter 13A: Topic 13A – The Boltzmann Distribution
  • 13A: Discussion Questions
  • 13A: Exercises
  • 13A: Problems
  • 13A: Extra Problems
  
  
• Chapter 13B: Topic 13B – Molecular Partition Functions
  • 13B: Discussion Questions
  • 13B: Exercises
  • 13B: Problems
  • 13B: Extra Problems
  
  
• Chapter 13C: Topic 13C – Molecular Energies
  • 13C: Discussion Questions
  • 13C: Exercises
  • 13C: Problems
  • 13C: Extra Problems
  
  
• Chapter 13D: Topic 13D – The Canonical Ensemble
  • 13D: Discussion Questions
  • 13D: Exercises
  • 13D: Problems
  • 13D: Extra Problems
  
  
• Chapter 13E: Topic 13E – The Internal Energy and the Entropy
  • 13E: Discussion Questions
  • 13E: Exercises
  • 13E: Problems
  • 13E: Extra Problems
  
  
• Chapter 13F: Topic 13F – Derived Functions
  • 13F: Discussion Questions
  • 13F: Exercises
  • 13F: Problems
  • 13F: Extra Problems
  
  
• Chapter 14: Focus 14 – Molecular Interactions
  • 14: Integrated Activities
  
  
• Chapter 14A: Topic 14A – The Electric Properties of Molecules
  • 14A: Discussion Questions
  • 14A: Exercises
  • 14A: Problems
  • 14A: Extra Problems
  
  
• Chapter 14B: Topic 14B – Interactions Between Molecules
  • 14B: Discussion Questions
  • 14B: Exercises
  • 14B: Problems
  • 14B: Extra Problems
  
  
• Chapter 14C: Topic 14C – Liquids
  • 14C: Discussion Questions
  • 14C: Exercises
  • 14C: Problems
  • 14C: Extra Problems
  
  
• Chapter 14D: Topic 14D – Macromolecules
  • 14D: Discussion Questions
  • 14D: Exercises
  • 14D: Problems
  • 14D: Extra Problems
  
  
• Chapter 14E: Topic 14E – Self-Assembly
  • 14E: Discussion Questions
  • 14E: Exercises
  • 14E: Problems
  • 14E: Extra Problems
  
  
• Chapter 15: Focus 15 – Solids
  • 15: Integrated Activities
  
  
• Chapter 15A: Topic 15A – Crystal Structure
  • 15A: Discussion Questions
  • 15A: Exercises
  • 15A: Problems
  • 15A: Extra Problems
  
  
• Chapter 15B: Topic 15B – Diffraction Techniques
  • 15B: Discussion Questions
  • 15B: Exercises
  • 15B: Problems
  • 15B: Extra Problems
  
  
• Chapter 15C: Topic 15C – Bonding in Solids
  • 15C: Discussion Questions
  • 15C: Exercises
  • 15C: Problems
  • 15C: Extra Problems
  
  
• Chapter 15D: Topic 15D – The Mechanical Properties of Solids
  • 15D: Discussion Questions
  • 15D: Exercises
  • 15D: Problems
  • 15D: Extra Problems
  
  
• Chapter 15E: Topic 15E – The Electrical Properties of Solids
  • 15E: Discussion Questions
  • 15E: Exercises
  • 15E: Problems
  • 15E: Extra Problems
  
  
• Chapter 15F: Topic 15F – The Magnetic Properties of Solids
  • 15F: Discussion Questions
  • 15F: Exercises
  • 15F: Problems
  • 15F: Extra Problems
  
  
• Chapter 15G: Topic 15G – The Optical Properties of Solids
  • 15G: Discussion Questions
  • 15G: Exercises
  • 15G: Problems
  • 15G: Extra Problems
  
  
• Chapter 16: Focus 16 – Molecules in Motion
  • 16: Integrated Activities
  
  
• Chapter 16A: Topic 16A – Transport Properties of a Perfect Gas
  • 16A: Discussion Questions
  • 16A: Exercises
  • 16A: Problems
  • 16A: Extra Problems
  
  
• Chapter 16B: Topic 16B – Motion in Liquids
  • 16B: Discussion Questions
  • 16B: Exercises
  • 16B: Problems
  • 16B: Extra Problems
  
  
• Chapter 16C: Topic 16C – Diffusion
  • 16C: Discussion Questions
  • 16C: Exercises
  • 16C: Problems
  • 16C: Extra Problems
  
  
• Chapter 17: Focus 17 – Chemical Kinetics
  • 17: Integrated Activities
  
  
• Chapter 17A: Topic 17A – The Rates of Chemical Reactions
  • 17A: Discussion Questions
  • 17A: Exercises
  • 17A: Problems
  • 17A: Extra Problems
  
  
• Chapter 17B: Topic 17B – Integrated Rate Laws
  • 17B: Discussion Questions
  • 17B: Exercises
  • 17B: Problems
  • 17B: Extra Problems
  
  
• Chapter 17C: Topic 17C – Reactions Approaching Equilibrium
  • 17C: Discussion Questions
  • 17C: Exercises
  • 17C: Problems
  • 17C: Extra Problems
  
  
• Chapter 17D: Topic 17D – The Arrhenius Equation
  • 17D: Discussion Questions
  • 17D: Exercises
  • 17D: Problems
  • 17D: Extra Problems
  
  
• Chapter 17E: Topic 17E – Reaction Mechanisms
  • 17E: Discussion Questions
  • 17E: Exercises
  • 17E: Problems
  • 17E: Extra Problems
  
  
• Chapter 17F: Topic 17F – Examples of Reaction Mechanisms
  • 17F: Discussion Questions
  • 17F: Exercises
  • 17F: Problems
  • 17F: Extra Problems
  
  
• Chapter 17G: Topic 17G – Photochemistry
  • 17G: Discussion Questions
  • 17G: Exercises
  • 17G: Problems
  • 17G: Extra Problems
  
  
• Chapter 18: Focus 18 – Reaction Dynamics
  • 18: Integrated Activities
  
  
• Chapter 18A: Topic 18A – Collision Theory
  • 18A: Discussion Questions
  • 18A: Exercises
  • 18A: Problems
  • 18A: Extra Problems
  
  
• Chapter 18B: Topic 18B – Diffusion-Controlled Reactions
  • 18B: Discussion Questions
  • 18B: Exercises
  • 18B: Problems
  • 18B: Extra Problems
  
  
• Chapter 18C: Topic 18C – Transition-State Theory
  • 18C: Discussion Questions
  • 18C: Exercises
  • 18C: Problems
  • 18C: Extra Problems
  
  
• Chapter 18D: Topic 18D – The Dynamics of Molecular Collisions
  • 18D: Discussion Questions
  • 18D: Exercises
  • 18D: Problems
  • 18D: Extra Problems
  
  
• Chapter 18E: Topic 18E – Electron Transfer in Homogeneous Systems
  • 18E: Discussion Questions
  • 18E: Exercises
  • 18E: Problems
  • 18E: Extra Problems
  
  
• Chapter 19: Focus 19 – Processes at Solid Surfaces
  • 19: Integrated Activities
  
  
• Chapter 19A: Topic 19A – An Introduction to Solid Surfaces
  • 19A: Discussion Questions
  • 19A: Exercises
  • 19A: Problems
  • 19A: Extra Problems
  
  
• Chapter 19B: Topic 19B – Adsorption and Desorption
  • 19B: Discussion Questions
  • 19B: Exercises
  • 19B: Problems
  • 19B: Extra Problems
  
  
• Chapter 19C: Topic 19C – Heterogeneous Catalysis
  • 19C: Discussion Questions
  • 19C: Exercises
  • 19C: Problems
  • 19C: Extra Problems
  
  
• Chapter 19D: Topic 19D – Processes at Electrodes
  • 19D: Discussion Questions
  • 19D: Exercises
  • 19D: Problems
  • 19D: Extra Problems